Publications
L. Ackermann,* "Transition Metal-Catalyzed Direct Arylations via C–H Bond Cleavages" Pure Appl. Chem. 2010, 82, accepted for publication. |
|
L. Ackermann,* A. R. Kapdi, H. K. Potukuchi, S. I. Kozhushkov "Syntheses via C-H Bond Functionalizations", in Handbook of Green Chemistry (Volume-Eds.: C.-J. Li, B. M. Trost), Wiley-VCH, 2010, Weinheim, in press. |
|
L. Ackermann,* R. Vicente, A. Kapdi, "Transition Metal-Catalyzed Direct Arylations of (Hetero)Arenes via C–H Bond Cleavages" Angew. Chem. Int. Ed. 2009, 48, in press. |
|
L. Ackermann,* R. Vicente, "Ruthenium-Catalyzed Direct Arylations through C-H Bond Cleavages" Top. Curr. Chem. 2009, DOI:10.1007/128_2009_9. Abstract/Fulltext>> |
|
L. Ackermann,* P. Novák, "Regioselective Ruthenium-Catalyzed Direct Benzylations of Arenes through C–H Bond Cleavages" Org. Lett. 2009, 11, 4966-4969. Abstract/Fulltext>> |
|
L. Ackermann,* R. Vicente, "Catalytic Direct Arylations in Polyethylene Glycol (PEG): Recyclable Palladium(0) Catalyst for C–H Bond Cleavages in the Presence of Air" Org. Lett. 2009, 11, 4922-4925. Abstract/Fulltext>> |
|
L. Ackermann,* R. Vicente, N. Hofmann, "Air-Stable Secondary Phosphine Oxide as Preligand for Palladium-Catalyzed Intramolecular α-Arylations with Chloroarenes" Org. Lett. 2009, 11, 4274–4276. Abstract/Fulltext>> |
|
L. Ackermann,* P. Novák, R. Vicente, N. Hofmann, "Ruthenium-Catalyzed Regioselective Direct Alkylation of Arenes with Unactivated Alkyl Halides through C-H Bond Cleavage" Angew. Chem. 2009, 121, 6161–6164; Angew. Chem. Int. Ed. 2009, 48, 6045–6048. Abstract>> (selected as - |
|
L. Ackermann,* H. K. Potukuchi, "Palladium-Catalyzed Cross-Coupling Reactions of 2-Pyridylborates with Air-Stable HASPO Preligands" Synlett 2009, 2852-2856. Abstract/Fulltext>> |
|
L. Ackermann,* A. Althammer, Peter Mayer, "Palladium-Catalyzed Direct Arylation-Based Domino Synthesis of Annulated
N-Heterocycles Using Alkenyl or (Hetero)Aryl 1,2-Dihalides" Synthesis 2009, 3493-3503. Abstract>> |
|
L. Ackermann,* R. Sandmann, M. Schinkel, M. V. Kondrashov, "Palladium-Catalyzed Sequential Indole Synthesis Using Sterically Hindered Amines" Tetrahderon (Symposia in print) 2009, 65, 8930–8939. Abstract/Fulltext>> |
|
L. Ackermann,* S. Barfüßer, H. K. Potukuchi, "Copper-Catalyzed N-Arylation/Hydroamin(d)ation Domino Synthesis of Indoles and its Application to the Preparation of a Chek1/KDR Kinase Inhibitor Pharmacophore" Adv. Synth. Catal. 2009, 351, 1064-1072. Abstract/Fulltext>> (highlighted in Synfacts 2009, 836) |
|
D. Facoetti, G. Abbiati, L. d'Avolio, L. Ackermann, E. Rossi,* "Novel Domino Approach to Fluorescent Pyrimido[1,6-a]indolones" Synlett 2009, 2273-2276. Abstract/Fulltext>> |
|
L. Ackermann,* R. Sandmann, L. T. Kaspar, "Two Titanium-Catalyzed Reaction Sequences for Syntheses of Pyrroles from (E/Z)-Chloroenynes or α-Haloalkynols" Org. Lett. 2009, 11, 2031-2034. Abstract/Fulltext>>(highlighted in Synfacts 2009, 718) |
|
L. Ackermann,* R. Sandmann, M. V. Kondrashov, "Thieme chemistry journal awardees - where are they now? Palladium-Catalyzed N-Arylation/Hydroamination Sequence for the Synthesis of Indoles with Sterically Demanding N-Substiuents" Synlett 2009, 1219-1222. Abstract/Fulltext>> |
|
L. Ackermann,* A. Althammer, S. Fenner, "Palladium-Catalyzed Direct Arylations of Heteroarenes with Tosylates and Mesylates" Angew. Chem. 2009, 121, 207–210; Angew. Chem. Int. Ed. 2009, 48, 201–204. Abstract>> (selected as - |
|
L. Ackermann,* R. Born, R. Vicente, "Ruthenium-Catalyzed Direct Arylations of N-Aryl 1,2,3-Triazoles with Aryl Chlorides as Electrophiles" ChemSusChem 2009, 546-549. Abstract/Fulltext>> |
|
L. Ackermann,* A. Althammer, "Moderne Magnesiumorganische Chemie. Neues von der Grignard-Reaktion", Chemie in Unserer Zeit 2009, 43, 74-83. Abstract>> |
|
L. Ackermann,* S. Barfüßer, "Palladium-Catalyzed Direct C-3 Arylations of Indoles with an Air-Stable HASPO" Synlett 2009, 808–812. Abstract/Fulltext>> |
|
L. Ackermann,* R. Vicente, "Sustainable Ruthenium-Catalyzed Direct Arylations through C-H Bond Functionalizations", in Experiments in Green and Sustainable Chemistry (Eds.: H. W. Roesky, D. Kennepohl), Wiley-VCH, Weinheim, 2009, 64–69. link to Wiley-VCH>> |
|
L. Ackermann,* R. Born, "Mizoroki-Heck Reactions with Metals other than Palladium", in The Mizoroki-Heck Reaction (Ed.: M. Oestreich), Wiley, Chichester, 2009, 383-403. link to Wiley-VCH>> |
|
L. Ackermann,* R. Vicente, "Metal-Catalyzed Direct Arylations", in Modern Arylation Methods (Ed.: L. Ackermann), Wiley-VCH, Weinheim, 2009, 311-333. link to Wiley-VCH>> |
 |
L. Ackermann,* "Arylation Reactions: A Historical Perspective", in Modern Arylation Methods (Ed.: L. Ackermann), Wiley-VCH, Weinheim, 2009, 1-24. link to Wiley-VCH>> |
|
L. Ackermann (Ed.), "Modern Arylation Methods", Wiley-VCH, Weinheim, January 2009, 543 pages. ISBN: 978-3-527-31937-4. link to Wiley-VCH>>; (For a review, see: M. Hapke, Angew. Chem. Int. Ed. 2009, 48, 6768. Abstract>>) |
|
L. Ackermann,* M. Mulzer, "Dehydrative Direct Arylations of Arenes with Phenols via Ruthenium-Catalyzed C−H and C−OH Bond Functionalizations" Org. Lett. 2008, 10, 5043-5045. Abstract/Fulltext>> |
|
S. I. Kozhushkov, D. S. Yufit, L. Ackermann,* "Ruthenium-Catalyzed Hydroarylations of Methylenecyclopropanes: Mild C−H Bond Functionalizations with Conservation of Cyclopropane Rings" Org. Lett. 2008, 10, 3409-3412. Abstract/Fulltext>> |
|
L. Ackermann,* H. K. Potukuchi, D. Landsberg, R. Vicente, "Copper-Catalyzed “Click” Reaction/Direct Arylation Sequence: Modular Syntheses of 1,2,3-Triazoles" Org. Lett. 2008, 10, 3081-3084. Abstract/Fulltext>> |
|
L. Ackermann,* R. Vicente, A. Althammer, "Assisted Ruthenium-Catalyzed C−H Bond Activation: Carboxylic Acids as Cocatalysts for Generally Applicable Direct Arylations in Apolar Solvents" Org. Lett. 2008, 10, 2299-2302. Abstract/Fulltext>> |
|
L. Ackermann,*
A. Althammer, R. Born, "[RuCl3(H2O)n]-catalyzed
direct arylations" Tetrahedron (Symposia in print) 2008, 64, 6115-6124. Abstract/Fulltext>> |
|
L. Ackermann,* "Chiral Secondary Phosphine Oxides as Preligands", in Trivalent Phosphorus Compounds in Asymmetric Catalysis, Synthesis and Applications Ed.: A. Börner), Wiley-VCH, Weinheim, 2008, 831-847. link to Wiley-VCH>> |
|
L. Ackermann,* A. Althammer "Phosphoric Acid Diesters as Efficient Catalysts for Hydroaminations of Nonactivated Alkenes and an Application to Asymmetric Hydroaminations", Synlett 2008, 995-998. Abstract/Fulltext>>; (highlighted in Synfacts 2008, 639) |
|
L. Ackermann,*
R. Vicente, R. Born, "Palladium-Catalyzed Direct
Arylations of 1,2,3-Triazoles with Aryl Chlorides Using Conventional Heating"
Adv. Synth. Catal. 2008, 350, 741-748. Abstract/Fulltext>> |
|
L. Ackermann,*
R. Sandmann, A. Villar, L. T. Kaspar, "Annulation
of internal alkynes through a hydroamination/aza-Heck reaction sequence
for the regioselective synthesis of indoles" Tetrahedron (Symposia
in print) 2008, 64, 769-777. Abstract/Fulltext>>; (highlighted in Synfacts 2008, 355) |
|
|
|
|
L. Ackermann,*
"Chelation-Assisted Arylation via C-H Bond Cleavage",
in Top. Organomet. Chem. 2007, 24,
35-60. Abstract |
|
L. Ackermann,*
A. Althammer, R. Born, "[RuCl3(H2O)n]-Catalyzed
Direct Arylations with Bromides as Electrophiles" Synlett
2007, 2833-2836. Table
of Contents>> |
|
L. Ackermann,* R. Born, P. Álvarez-Bercedo, "Ruthenium(IV) Alkylidenes as Precatalysts for Direct Arylations of Alkenes with Aryl Chlorides and an Application to Sequential Catalysis" Angew. Chem. 2007, 119, 6482–6485; Angew. Chem. Int. Ed. 2007, 46, 6364–6367. Abstract>> (chosen as -  Hot paper -) |
|
L. Ackermann,*
L. T. Kaspar, "TiCl4-Catalyzed Indirect
Anti-Markovnikov Hydration of Alkynes: Application to the Synthesis of
Benzo[b]furans" J. Org. Chem. 2007, 72,6149-6153. Abstract>>; highlighted in Organic Chemistry Portal>> |
|
L. Ackermann,*
L. T. Kaspar, A. Althammer, "Hydroaminations of Unactivated
Alkenes with Basic Alkylamines: Group 4 Metal Halide Catalysts and Brønsted-Acid
Organocatalysts" Org. Biomol. Chem. 2007, 5, 1975-1978.
Abtract>> |
|
L. Ackermann,*
"Catalytic Arylations with Challenging Substrates: From Air-Stable
HASPO Preligands to Indole Syntheses and C-H-Bond Functionalizations"
Synlett 2007, 507-526. Table of Contents>> |
|
|
|
|
L. Ackermann,*
J. H. Spatz, C. J. Gschrei, R. Born, A. Althammer,
"A Diaminochlorophosphine for Palladium-Catalyzed Arylations of
Amines and Ketones" Angew. Chem. 2006, 118,
7789-7792; Angew. Chem. Int. Ed. 2006, 45, 7627-7630.
Abstract>> |
|
L. Ackermann,*
A. Althammer, "Air-Stable PinP(O)H as Preligand for Palladium-Catalyzed
Kumada Couplings of Unactivated Tosylates" Org. Lett. 2006,
8, 3457-3460. Abstract>>; highlighted in Organic Chemistry Portal>> |
|
L. Ackermann,*
A. Althammer, "One-pot indole synthesis consisting of a ruthenium-catalyzed
hydroamination and a palladium-catalyzed Heck reaction using 2-chloroaniline"
Synlett 2006, 3125-3129. Table
of Contents>> |
|
L. Ackermann,*
C. J. Gschrei, A. Althammer, M. Riederer, "Cross-coupling
reactions of aryl and vinyl chlorides catalyzed by a palladium complex
derived from an air-stable H-phosphonate" Chem. Commun. 2006,
1419-1421. Abstract>> |
|
L. Ackermann,*
"Air- and Moisture-Stable Secondary Phosphine Oxides as Preligands
in Catalysis" Synthesis 2006, 1557-1571.
Table
of Contents>> |
|
L. Ackermann,*
A. Althammer, R. Born, "Catalytic Arylation Reactions
by C-H Bond Activation with Aryl Tosylates" Angew. Chem.2006,
118, 2681-2685; Angew. Chem. Int. Ed. 2006, 45,
2619-2622. Abstract/Fulltext>> |
|
L. Ackermann,*
R. Born, J. H. Spatz, A. Althammer, C. J. Gschrei "Air-Stable
Phosphine Oxides as Preligands for Catalytic Activation Reactions of C-Cl-,
C-F- and C-H-Bonds" Pure Appl. Chem. 2006, 78,
209-214. Abstract>> |
|
|
|
|
L. Ackermann,*
R. Born, J. H. Spatz, D. Meyer, "Efficient Aryl-(Hetero)Aryl
Coupling via Activation of C-Cl and C-F Bonds Using Nickel Complexes of
Air-Stable Phosphine Oxides" Angew. Chem. 2005,
117,7382-7386; Angew. Chem. Int. Ed. 2005, 44,
7216-7219. Abstract/Fulltext>> (chosen as - Hot
paper -) |
|
L. T. Kaspar,
L. Ackermann,* "Three-component indole synthesis using ortho-dihaloarenes"
Tetrahedron (Symposia in print) 2005, 61, 11311-11316. Abstract/Fulltext>>; highlighted in Organic Chemistry Portal>> |
|
L. T. Kaspar,
B. Fingerhut, L. Ackermann,* "Titanium-Catalyzed Intermolecular
Hydroamination of Vinylarenes" Angew. Chem. 2005,
117, 6126-6128; Angew. Chem. Int. Ed. 2005, 44,
5972-5974. Abstract/Fulltext>> |
|
L. Ackermann,*
"Phosphine Oxides as Preligands in Ruthenium-Catalyzed Arylations
via C-H-Bond Functionalization Using Aryl Chlorides"
Org. Lett. 2005, 7, 3123-3125. Abstract>> |
|
|
L. Ackermann,*
R. Born, "Modular Diamino and Dioxophosphine Oxides and
Chlorides as Ligands for Transition-Metal-Catalyzed C-C and C-N Bond
Formations Using Aryl Chlorides" Angew. Chem. 2005,
117, 2497-2500; Angew. Chem. Int. Ed. 2005, 44,
2444-2447. Abstract/Fulltext>>
|
|
L. Ackermann,*
"General and Efficient Indole Syntheses Based on Catalytic Amination
Reactions", Org. Lett. 2005, 7, 439-442.
Abstract>> |
|
| |
|
L. Ackermann,*
L. T. Kaspar, C. J. Gschrei, "Hydroamination/Heck reaction sequence for a highly regioselective one-pot synthesis of indoles using 2-chloroaniline", Chem. Commun. 2004, 2824-2825.
Article>> |
|
|
L. Ackermann,* R. Born, "TiCl4/t-BuNH2 as the sole catalyst for a hydroamination-based Fischer indole synthesis", Tetrahderon Lett. 2004, 45, 9541-9544. Abstract/Fulltext>>
|
|
L. Ackermann,*
L. T. Kaspar, C. J. Gschrei "TiCl4-Catalyzed Intermolecular Hydroamination Reactions
of Norbornene", Org. Lett.2004, 6, 2515-2518. Abstract>> |
|
|
|
|
L. Ackermann,*
"TiCl4-catalyzed Intermolecular Hydroamination
Reactions", Organometallics 2003, 22, 4367-4368.
Abstract>> |
|
| L. Ackermann,
R. G. Bergman, R. N. Loy, "Use of Group 4 Bis(sulfonamido)
Complexes in the Intramolecular Hydroamination of Alkynes and Allenes", J. Am. Chem. Soc. 2003, 125, 11956-11963. |
|
|
|
|
| L. Ackermann,
R. G. Bergman, "A Highly Reactive Titanium Precatalyst for Intramolecular
Hydroamination Reactions", Org. Lett. 2002, 4,
1475-1478. |
|
|
|
|
| A. Fürstner,
H. Krause, L. Ackermann, C. W. Lehmann, "N-Heterocyclic
carbenes can coexist with alkenes and C-H acidic sites", Chem.
Commun. 2001, 2240-2241. |
|
| A. Fürstner,
L. Ackermann, B. Gabor, R. Goddard, C. W. Lehmann,
R. Mynott, F. Stelzer, O. R. Thiel, "Comparative Investigation
of Ruthenium-Based Metathesis Catalysts Bearing N-Heterocyclic
Carbene (NHC) Ligands", Chem. Eur. J. 2001, 7,
3236-3253. |
|
| A. Fürstner,
L. Ackermann, K.n Beck, H. Hori, D. Koch, K. Langemann,
M. Liebl, C. Six, W. Leitner, "Olefin Metathesis in
Supercritical Carbon Dioxide", J. Am. Chem. Soc. 2001,
123, 9000-9006. |
|
| L. Ackermann,
C. Bruneau, P. H. Dixneuf, "Simple New Three-component
Catalytic System for Enyne Metathesis ", Synlett 2001,
397-399. |
|
| A. Fürstner,
O. R. Thiel, L. Ackermann, "Exploiting the Reversibility of
Olefin Metathesis. Synthesis of Macrocyclic Trisubstituted Alkenes and
(R,R)-(-)-Pyrenophorin", Org. Lett. 2001,
3, 449-451. |
|
|
|
|
| L. Ackermann,
D. El Tom, A. Fürstner, "Ruthenium Carbene Complexes with
Imidazol-2-ylidene Ligands: Syntheses of Conduritol Derivatives Reveals
Superior RCM Activity", Tetrahderon 2000, 56,
2195-2202. |
|
| A. Fürstner,
O. R. Thiel, L. Ackermann, H.-J. Schanz, S. P. Nolan,
"Ruthenium Carbene Complexes with N,N'-Bis(mesityl)imidazol-2-ylidene
Ligands: RCM Catalysts of Extended Scope", J. Org. Chem. 2000,
65, 2204-2207. |
|
|
|
|
| L. Ackermann, A. Fürstner, T. Weskamp, F. J. Kohl, W. A. Herrmann, "Ruthenium carbene complexes with imidazolin-2-ylidene ligands allow the formation of tetrasubstituted cycloalkenes by ring-closing metathesis (RCM)", Tetrahedron Lett. 1999, 40, 4787-4790. |
|
| A. Fürstner,
L. Ackermann, "A most user-friendly protocol for ring-closing metathesis
reactions", Chem. Commun. 1999, 95-96. |
|
| L. Ackermann,
A. Heidbreder, F. Wurche, F.-G. Klärner, J. Mattay,
"Mechanistic Studies on PET-oxidative cyclization of unsaturated
silyl enol ethers: dependence of the regioselectivity on alcohol addition
and pressure effects", Perkin Trans. 2 1999, 863-869. |
|
Additional publications |
| A. Althammer, L. Ackermann, "Hochschule trifft Industrie" Nachr. Chem. 2008, 56, 71. |
| L. Ackermann, "The Claisen Rearrangement. Methods and Applications" Nachr. Chem. 2007, 55, 899. |
| L. Ackermann, "Bürgenstock 2005" Nachr. Chem. 2005, 53, 817. |
| L. Ackermann,
"Development of Air-Stable Heteroatom-Substituted Secondary Phosphine
Oxides (HASPO) as Preligands for Catalytic Coupling Reactions" -
Habilitation, München 2007. |
| L. Ackermann,
"Entwicklung und Anwendung neuartiger Präkatalysatoren für
die Olefinmetathese" - Dissertation, Der Andere Verlag 2001,
ISBN: 3935316585. |
PDF-files of some articles (to view use Acrobat Reader) are available via the journal homepage.